Webπ-Expanded oligothienylene macrocycle with a large inner cavity incorporates fullerenes such as methano[60]fullerene (C61H2) and [70]fullerene (C70) inside to form Saturn-like complexes. Although the oligothiophene macrocycle weakly interacts with fullerenes in solution, it forms stable Saturn-like fullerene complexes in the solid state. X-ray analysis … WebMar 17, 2024 · The highest number of 30 C-Hπ interactions between the [Cu10(Mim)10] disk and the C60/C70 surfaces drives the formation of the nano-Saturns. The calculated …
Photoinduced Electron Transfer in a Dynamic Supramolecular …
WebFeb 11, 2024 · Abstract. The first disk-type nano-Saturn complexes, [Cu10 (Mim)10] C60 and [Cu10 (Mim)10] C70 (Mim = 2-methylimidazolate), were assembled under one-pot … WebThe first disk-type nano-Saturn complexes, [Cu10(Mim)10] C60 and [Cu10(Mim)10] C70 (Mim = 2-methylimidazolate), were assembled under one-pot solvothermal conditions. pinellas county govt jobs
Figure 6. (a,b) 1 HN MR spectrai n[D 6 ]DMSO of 8 and C 60 &9...
WebMay 30, 2024 · This disk-shaped host included a C60 guest in 1:1 ratio to form a Saturn-type supra... Nano‐Saturn: Experimental Evidence of Complex Formation of an … WebSince the discovery in 1985, 1 fullerene-C 60 (C 60, buckyball) and its derivatives have always been a research hotspot because of their unique structures and physicochemical … WebMar 1, 2024 · This website requires cookies, and the limited processing of your personal data in order to function. By using the site you are agreeing to this as outlined in our pinellas county graduation requirements